trans-(4-Acetylnaphthyl)chloridobis(triphenylphosphine-κP)nickel(II) dichloromethane solvate
نویسندگان
چکیده
The title compound, [Ni(C(12)H(9)O)Cl(C(18)H(15)P)(2)]·CH(2)Cl(2), was synthesized from the reaction between 1-acetyl-4-chloro-naphthalene, NiCl(2)·6H(2)O and triphenyl-phosphine (PPh(3)) in ethanol. The compound contains one crystallographically unique nickel ion in a pseudo-square-planar geometry.
منابع مشابه
[(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triphenylphosphine-κP)gold(I) dichloromethane solvate
An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S-Au-P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra-molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C-H⋯S, C-H⋯N and C-H⋯O contacts.
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The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.
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In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl-phosphine (PPh(3)) ligands, one dihydro-bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octa-hedra. The two P atoms of the PPh(3) ligands are tran...
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In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octa-hedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-H⋯Cl hydrogen bonds link the complex cations and Cl(-) ...
متن کامل(Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN 2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate. Corrigendum
The author list in the paper by Tong, Hung, Wang, Lin & Lo [Acta Cryst. (2009), E65, m438] is corrected.[This corrects the article DOI: 10.1107/S1600536809010265.].
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